The conversion of COx into value-added inexperienced aromatics is taken into account as a promising route to realize the world’s decarbonization resulting from its appreciable thermodynamic driving pressure and atomic economic system the place low H/C ratio aromatics are chosen as a product. It’s enabled by bifunctional nano-catalysts composed of metallic oxides with plentiful oxygen vacancies and acid zeolites, thus realizing superior selectivity in hydrocarbons on the single cross of COx conversion. On this mini-review, we primarily present some thought-provoking insights on the nanoscale of this difficult course of together with the proximity of lively websites, response mechanism, uneven desorption habits of intermediates and closing merchandise and general thermodynamic evaluation. The facile floor diffusion of intermediates owing to the proximity of lively websites stimulates the response, which follows an autocatalytic course of. This optimistic suggestions attributed to the autocatalytic cycle accelerates the transformation of vitality and supplies within the thermodynamically optimum route, making the response extremely selective in the direction of the ultimate merchandise. This difficult coupling course of, like a nano-maze constituted by these micro-environment elements, is difficult when it comes to the response pathway however extremely selective to a set route guided by general thermodynamics. Deep understanding of such an autocatalytic cycle on the nanoscale paves the way in which for the rational design of next-generation high-performance catalysts.