Synthesis of novel inflexible buildings derived from 1,1′-biadamantane: Fullerenes, Nanotubes and Carbon Nanostructures: Vol 0, No 0


At the moment adamantane, the best diamondoid, has attracted a lot consideration, attributable to its distinctive construction and properties for the development of nanostructured entities. 1,1′-biadamantane is a virtually inflexible hydrocarbon fashioned from the covalent attachment of the 2 adamantane items. On this research, adamantane was first transformed to 1,1′-biadamantane, and the obtained 1,1′-biadamantane was brominated to offer its hexabromo spinoff. The six bromine atoms within the hexabromo spinoff had been then substituted by six phenols by way of a Friedel-Crafts alkylation response to yield the novel hexakis (4-hydroxyphenyl) spinoff. Additionally, hydrolysis of the heaxabromo spinoff afforded the novel hexahydroxy spinoff.

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